Effect of Mg doping on the superconducting properties of Cu/sub 1-x/Tl/sub x/Ba/sub 2/Ca/sub 3-y/Mg/sub y/Cu/sub 4/O/sub 12-/spl delta//

Superconducting properties of Cu/sub 1-x/Tl/sub x/Ba/sub 2/Ca/sub 3-y/Mg/sub y/Cu/sub 4/O/sub 12-/spl delta// (Cu/sub 1-x/Tl/sub x/Mg/sub y/-1234) material have been studied in the composition range y=0,1.5,2.25. The zero resistivity critical temperature [T/sub c/(R=0)] was found to increase with the increased concentration of Mg in the unit cell; for y=1.5 [T/sub c/(R=0)]=131 K was achieved which is hitherto highest in Cu/sub 1-x/Tl/sub x/-based superconductors. The X-ray diffraction analyses have shown the formation of a predominant single phase of Cu/sub 0.5/Tl/sub 0.5/Ba/sub 2/Ca/sub 3-y/Mg/sub y/Cu/sub 4/O/sub 12-/spl delta// superconductor with an inclusion of impurity phase. It is observed from the convex shape of the resistivity versus temperature measurements that our as-prepared material was in the region of carrier over-doping, and the number of carriers was optimized by postannealing experiments in air at 400/spl deg/C, 500/spl deg/C, and 600/spl deg/C. The T/sub c/(R=0) was found to increase with postannealing and the best postannealing temperature was found to be 600/spl deg/C. The mechanism of increased T/sub c/(R=0) is understood by carrying out infrared absorption measurements. It was observed through softening of Cu(2)-O/sub A/-Tl apical oxygen mode that improved interplane coupling was a possible source of enhancement of T/sub c/(R=0) to 131 K.     

Thermal-diffusion and diffusion-thermo effects on axisymmetric flow of a second grade fluid

This study investigates the thermal-diffusion and diffusion-thermo effects on the two-dimensional magnetohydrodynamics (MHD) axisymmertric flow of a second grade fluid. Mathematical analysis has been carried out in the presence of Joule heating and first order chemical reaction. Using momentum, energy and concentration laws, the governing partial differential equations have been reduced to the ordinary differential equations by suitable transformations. Series solutions are constructed by homotopy analysis method (HAM). Convergence of the derived series solutions is ensured. Plots are displayed in order to examine the influence of emerging parameters on the dimensionless components of velocity, temperature and concentration fields. Numerical computations for skin friction coefficient, Nusselt number and Sherwood number are tabulated.     

Failure Analysis of a Threaded Pipe Ruptured During Hydraulic Testing

In the present case study, failure analysis of a piping system that ruptured during hydraulic testing has been carried out to find the root cause and determine the mode and mechanism of failure. Chemical composition of the pipe was found to be in compliance with the standard composition of AISI4130. The failure cause of the pipe has been investigated through visual examination, microstructural observation, hardenability analysis, and fractography. Threaded grooves were produced through machining after heat treatment. Variation in hardness and strength through thickness (from case to core) was evaluated using standard hardenability graph. Hardenability analysis showed that the strength of the pipe after machining was still well above the calculated maximum stress at any point of piping system. This finding was further supported by the microstructural study. The actual cause of pipe failure during hydraulic test was found to be due to the stress concentration factor being developed by some notch from improper thread machining which lead brittle failure and was also revealed by fractography analysis.